| Table of Contents | Douglas B. Cameron |
Silver Clusters
| Casual Introduction and Abstract |
Introduction and Organization of the Thesis (Chapter 1)
An Introduction
Organization of the Thesis
Experimental Apparatus and Methods (Chapter 2)
Introduction
Phase 1
Experimental Apparatus
Timing
Phase 2
Ionization Potentials of Cold Silver Clusters (Chapter 3)
Introduction
Mass Spectra
Ionization Potential Determination
Discussion
A Deformed Sphere Model of the Electronic Structure
of Small Metallic Particles (Chapter 4)
Introduction
A Spherical Approximation: The Shell Model
Theoretical Description
Results
A Perturbed Sphere and the Loss of Symmetry
Ideas from Previous Models
Difficulties with Traditional Models
Theoretical Description
Results
Deformations and Local Minima
Computational Method
Agn+ Photodissociation (Chapter 5)
Introduction
Experiment
A Model of Metal Cluster Fragmentation
Introduction
The RRKM Model
Implementation of the Model
Fragmentation Energies
Path Degeneracy
Oscillator Frequency Distributions
Conversion to Canonical Distributions
Preliminary Experimental Results and Comparisons with the Model
Ag9+ Fragmentation
Other sizes
Spectroscopic Information
A Geometric Model of Electronic Structure: Icosahedral Structure of Metal Particles (Chapter 6)
Appendix I: Table of Ionization Potentials
Appendix II: Notes on Silver and Its Clusters
Douglas B. Cameron |