C60+
Reactions with Alkali Metals in an rf Trap |
LinC60+ Formation Rate Equations
Under the assumptions of decay rates independent of n (for n=0 and n>0) and insignificant dissociation rates, the formation rate equations can be expressed in a kinetic model with only two variables, k1 and M1(0), as shown on the right.
Determing k1 and M1(0) from the decay of LiC60+ permits the prediction of all other species (n=2-6). The plots below compare predicted values (curves) with observed ion counts. Close agreement confirms the single formation rate model.
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C60+
Reactions with Alkali Metals in an rf Trap |